I have set error_log = "/var/log/apache2/php_errors.log" and made sure errors were being logged. I have set the file to be owned by the www-data owner and group and even set the permissions to 777.

I have confirmed with phpinfo() that the error_log is correctly set, however The logging still only happens in my vhost's apache error log.

The following is my php.ini for 5.3.3-7 on Debian Squeeze Apache 2:

The top is populated with comments on what I have been interested, or have changed.

I have deleted all comments to save space. Full versions here: http://pastebin.com/AhWLiQBR

[PHP]

;short_open_tag = On
;allow_call_time_pass_reference = On
;error_reporting = E_ALL & ~E_NOTICE & ~E_DEPRECATED
;display_errors = On
;display_startup_errors = Off
;log_errors = On
;html_errors = On

error_log = "/var/log/apache2/php_errors.log"
engine = On
short_open_tag = On
asp_tags = Off
precision = 14
y2k_compliance = On
output_buffering = 4096
zlib.output_compression = Off
implicit_flush = Off
unserialize_callback_func =
serialize_precision = 100
allow_call_time_pass_reference = On
safe_mode = Off
safe_mode_gid = Off
safe_mode_include_dir =
safe_mode_exec_dir =
safe_mode_allowed_env_vars = PHP_
safe_mode_protected_env_vars = LD_LIBRARY_PATH
disable_functions =
disable_classes =
expose_php = On
max_execution_time = 30
max_input_time = 60
memory_limit = 128M
error_reporting = E_ALL & ~E_NOTICE & ~E_DEPRECATED
display_errors = On
display_startup_errors = Off
log_errors = On
log_errors_max_len = 1024
ignore_repeated_errors = Off
ignore_repeated_source = Off
report_memleaks = On
track_errors = Off
html_errors = On
variables_order = "GPCS"
request_order = "GPC"
register_globals = Off
register_long_arrays = Off
register_argc_argv = Off
auto_globals_jit = On
post_max_size = 100M
magic_quotes_gpc = Off
magic_quotes_runtime = Off
magic_quotes_sybase = Off
auto_prepend_file =
auto_append_file =
default_mimetype = "text/html"
doc_root =
user_dir =
enable_dl = Off
file_uploads = On
upload_tmp_dir = /tmp
upload_max_filesize = 100M
max_file_uploads = 20
allow_url_fopen = On
allow_url_include = Off
default_socket_timeout = 60
[Date]
[filter]
[iconv]
[intl]
[sqlite]
[sqlite3]
[Pcre]
[Pdo]
[Pdo_mysql]
pdo_mysql.cache_size = 2000
pdo_mysql.default_socket=
[Phar]
[Syslog]
define_syslog_variables  = Off
[mail function]
SMTP = localhost
smtp_port = 25
mail.add_x_header = On
[SQL]
sql.safe_mode = Off
[ODBC]
odbc.allow_persistent = On
odbc.check_persistent = On
odbc.max_persistent = -1
odbc.max_links = -1
odbc.defaultlrl = 4096
odbc.defaultbinmode = 1
[Interbase]
ibase.allow_persistent = 1
ibase.max_persistent = -1
ibase.max_links = -1
ibase.timestampformat = "%Y-%m-%d %H:%M:%S"
ibase.dateformat = "%Y-%m-%d"
ibase.timeformat = "%H:%M:%S"
[MySQL]
mysql.allow_local_infile = On
mysql.allow_persistent = On
mysql.cache_size = 2000
mysql.max_persistent = -1
mysql.max_links = -1
mysql.default_port =
mysql.default_socket =
mysql.default_host =
mysql.default_user =
mysql.default_password =
mysql.connect_timeout = 60
mysql.trace_mode = Off
[MySQLi]
mysqli.max_persistent = -1
mysqli.allow_persistent = On
mysqli.max_links = -1
mysqli.cache_size = 2000
mysqli.default_port = 3306
mysqli.default_socket =
mysqli.default_host =
mysqli.default_user =
mysqli.default_pw =
mysqli.reconnect = Off
[mysqlnd]
mysqlnd.collect_statistics = On
mysqlnd.collect_memory_statistics = Off
[OCI8]
[PostgresSQL]
pgsql.allow_persistent = On
pgsql.auto_reset_persistent = Off
pgsql.max_persistent = -1
pgsql.max_links = -1
pgsql.ignore_notice = 0
pgsql.log_notice = 0
[Sybase-CT]
sybct.allow_persistent = On
sybct.max_persistent = -1
sybct.max_links = -1
sybct.min_server_severity = 10
sybct.min_client_severity = 10
[bcmath]
bcmath.scale = 0
[browscap]
[Session]
session.save_handler = files
session.use_cookies = 1
session.use_only_cookies = 1
session.name = PHPSESSID
session.auto_start = 0
session.cookie_lifetime = 0
session.cookie_path = /
session.cookie_domain =
session.cookie_httponly =
session.serialize_handler = php
session.gc_probability = 0
session.gc_divisor = 1000
session.gc_maxlifetime = 1440
session.bug_compat_42 = Off
session.bug_compat_warn = Off
session.referer_check =
session.entropy_length = 0
session.cache_limiter = nocache
session.cache_expire = 180
session.use_trans_sid = 0
session.hash_function = 0
session.hash_bits_per_character = 5
url_rewriter.tags = "a=href,area=href,frame=src,input=src,form=fakeentry"
[MSSQL]
mssql.allow_persistent = On
mssql.max_persistent = -1
mssql.max_links = -1
mssql.min_error_severity = 10
mssql.min_message_severity = 10
mssql.compatability_mode = Off
mssql.secure_connection = Off
[Assertion]
[COM]
[mbstring]
[gd]
[exif]
[Tidy]
tidy.clean_output = Off
[soap]
soap.wsdl_cache_enabled=1
soap.wsdl_cache_dir="/tmp"
soap.wsdl_cache_ttl=86400
soap.wsdl_cache_limit = 5
[sysvshm]
[ldap]
ldap.max_links = -1
[mcrypt]
[dba]