I've recently started using Windows (having used Ubuntu up until now) and I find myself unable to properly set environment variables. Whenever I set them they don't seem to work. I've been going to Start->Edit Environment Variables for your Account and editing the PATH value in the upper half of the GUI. Here's what I've got so far.

 ;C:\Chocolatey\bin;C:\tools\mysql\current\bin;C:\Program Files (x86)\Git\bin;C:\Program Files\MySQL\MySQL Server 5.6\bin\;C:\Python33\Scripts;

These are each the parent directories of the executables I'd like to be able to run by name from CMD, but mysql, git, and pip aren't being recognized. Am I doing something wrong syntactically or at a general understanding level? I'd like to be able to run these commands without having to specify the full path to the executables every time.

EDIT: The full PATH extracted from CMD

PATH=C:\Python33\;C:\Program Files (x86)\NVIDIA Corporation\PhysX\Common;C:\Program Files (x86)\AMD APP\bin\x86_64;C:\Program Files (x86)\AMD APP\bin\x86;C:\Program Files\Common Files\Microsoft Shared\Windows Live;C:\Program Files (x86)\Common Files\Microsoft Shared\Windows Live;C:\Windows\system32;C:\Windows;C:\Windows\System32\Wbem;C:\Windows\System32\WindowsPowerShell\v1.0\;C:\Program Files (x86)\GTK2-Runtime\bin;C:\Program Files\WIDCOMM\Bluetooth Software\;C:\Program Files\WIDCOMM\Bluetooth Software\syswow64;C:\Program Files (x86)\ATI Technologies\ATI.ACE\Core-Static;C:\Program Files (x86)\Microsoft ASP.NET\ASP.NET Web Pages\v1.0\;C:\Program Files\Microsoft SQL Server\110\Tools\Binn\;C:\Program Files (x86)\QuickTime\QTSystem\;C:\Program Files (x86)\Common Files\Acronis\SnapAPI\;C:\Program Files (x86)\Java\jre7\bin;C:\Program Files (x86)\Windows Kits\8.1\Windows Performance Toolkit\;C:\Program Files (x86)\Microsoft SDKs\TypeScript\;C:\Program Files (x86)\MySQL\MySQL Utilities 1.3.4\; ;C:\Chocolatey\bin;C:\tools\mysql\current\bin

I'm being forced to use Windows by my work environment, I don't enjoy the state of affairs.